若干水华相关藻类对太湖水体异味物质贡献的初步研究

太湖水体中嗅味物质2-甲基异莰醇(MIB)和土臭素(Geo)的出现与水华发生在时间上高度重叠,为探寻水华中常见藻类与嗅味的关系,本研究通过对实验室培养藻株和野外水样比较分析,探寻了部分藻株与太湖水体嗅味物质的关系.分析实验室培养的15株蓝藻(其中11株微囊藻)、4株绿藻和4株硅藻,仅硅藻培养物测定出了Geo,所有藻株均未检测出MIB;对太湖典型水样分析结果显示,水体中MIB与Geo的浓度与微囊藻细胞浓度无相关性;实验室模拟微囊藻水华腐败结果显示,无论是好氧还是厌氧条件下均未产生MIB和Geo;这些数据结果说明湖水中MIB和Geo与水华主要种群微囊藻无直接关系.在鱼腥藻水华中测出了高浓度的MIB,周年水样分析结果显示鱼腥藻细胞数与MIB浓度变化规律一致,因此鱼腥藻可能是MIB的重要来源.但实验室培养的Anabaena sp.PCC7120无论是在缺氮还是有氮培养条件下均不产MIB和Geo,说明嗅味物质的产生具有藻株特异性.     

袭港热带气旋持续时间长期频率分析

香港经常受到西北太平洋热带气旋的影响,对该地区热带气旋持续时间的研究有助于经济社会的稳定发展。按照气象和天文台警告信号,热带气旋分为不同的强度等级。建立热带气旋持续时间的Poisson-Weibull复合分布模型,相应获得持续时间重现值的求解公式,分别用于不同热带气旋分类下持续时间多年一遇重现值的计算中。基于1987-2016年袭港热带气旋数据的分析结果表明,Poisson-Weibull分布适用于不同的持续时间分类样本;强的热带气旋经常会伴随较长的持续时间,这将会对该地区造成更为严重的破坏,这可为防灾减灾提供参考。     

护坡桩+微型钢管桩复合土钉墙联合支护体系研究应用

本文提出了一种新的联合支护体系——护坡桩+微型钢管桩复合土钉墙支护体系,成功解决了基坑周边无放坡空间需垂直开挖、基坑深度大、要求位移小、支护费用高等技术难题,做到了施工便利,对控制边坡位移变形、增强边坡整体稳定性、保证在基坑开挖工程中不发生对周围环境的影响具有良好的作用。采用这种支护方式对北京一工程进行设计施工探讨,经工后监测效果良好,大大地提高了边坡的安全稳定性,从而验证了这一支护形式的可行性,其在深基坑支护中具有常规土钉墙和护坡桩无法相比的技术与经济优势,可供其他类似工程参考,具有较高的适用推广价值。     

复合动力钻进工艺在干热岩钻井中的应用研究

2011年山东省地矿局在山东省利津县实施了国内第一个干热岩调查评价项目,采用转盘回转钻进,但钻效低、能耗高。为提高在高温硬岩条件下的钻进效率、缩短钻井周期、降低生产成本,2015年在福建省漳州市实施的中国地质调查局东南沿海深部地热HDR-1干热岩科学钻探工程井（井深4000.86 m,孔底温度109 ℃）和2017年在青海省共和县完成的GR1干热岩科学勘探井（井深3705 m,孔底温度236 ℃）,在施工中均探索使用了“转盘+螺杆钻具”复合钻进工艺,并在高温取心段首次测试应用了“转盘+涡轮钻具”复合取心钻进工艺,取得了良好的效果并就下一步研究方向提出了意见和建议,为螺杆钻具和涡轮钻具的深入研究提供了宝贵的高温施工经验,也将为我国干热岩科学钻探与深部地热资源勘探提供新的技术支撑。     

辽宁北部秀水盆地秀D1井下白垩统义县组烃源岩生物标志化合物特征及意义

应用气相色谱、气相色谱-质谱技术,研究了秀水盆地秀D1井下白垩统义县组烃源岩的生物标志化合物特征,对烃源岩有机质来源、沉积环境、热演化程度等进行了分析.结果表明,秀水盆地秀D1井下白垩统义县组烃源岩有机质丰度高,有机质类型为Ⅱ型,处于成熟演化阶段;（C₂₀+C₂₁）/（C₂₃+C₂₄）三环萜烷为0.66~5.06,C₂₄四环萜烷/C₂₆三环萜烷为0.38~2.25,具有典型湖相烃源岩特征;烃源岩Pr/Ph主要介于0.5~1.0之间,指示还原环境;伽马蜡烷/C30藿烷比值为0.05~0.41之间,指示处于强还原性沉积环境,并且烃源岩沉积时水体的盐度较低以及可能存在水体盐度分层;Pr/nC₁₇、Ph/nC₁₈关系表明有机质类型主要为Ⅱ₁型,C₂₇-C₂₈-C₂₉甾烷的相互关系反映有机质来源应为低等水生生物和陆生高等植物的混合来源;Ts/Tm比值为0.45~1.82,C₃₁αβ22S/（22S+22R）比值为0.41~0.62,表明烃源岩处于低成熟-成熟演化阶段,并且具有义县组中、下部烃源岩成熟度较义县组上部高的特点.综合认为秀水盆地早白垩世义县组烃源岩形成于水体盐度较低的还原-强还原环境,有机质来源为混合来源,有利于有机质的富集,义县组具有较好的油气勘探前景.     

A statistical analysis of typhoon frequency and application in design wave height

A typhoon leading is an important natural disaster to many disasters to China. A giant wave caused by it has brought large threat for an offshore project. Based on the maximum entropy principle,one new model which has 4 undetermined parameters is constructed,which is called the discrete maximum entropy probabilistic model. In practical applications,the design wave height is considered as soon as possible in a typhoon affected sea areas,the result fits the observed data well. Further more this model does not have the priority compared with other distributions as Poisson distribution. The model provides a theoretical basis for the engineering design more reasonable when considering typhoon factors comprehensively.     

铁锰氧化物对苯酚氧化降解的实验研究

为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究.土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿.结果表明:苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的...     

Evolution and sedimentology of a channel fill in the sandy braided South Saskatchewan River and its comparison to the deposits of an adjacent compound bar

The depositional stratigraphy of within‐channel deposits in sandy braided rivers is dominated by a variety of barforms (both singular ‘unit’ bars and complex ‘compound’ bars), as well as the infill of individual channels (herein termed ‘channel fills’). The deposits of bars and channel fills define the key components of facies models for braided rivers and their within‐channel heterogeneity, knowledge of which is important for reservoir characterization. However, few studies have sought to address the question of whether the deposits of bars and channel fills can be readily differentiated from each other. This paper presents the first quantitative study to achieve this aim, using aerial images of an evolving modern sandy braided river and geophysical imaging of its subsurface deposits. Aerial photographs taken between 2000 and 2004 document the abandonment and fill of a 1·3 km long, 80 m wide anabranch channel in the sandy braided South Saskatchewan River, Canada. Upstream river regulation traps the majority of very fine sediment and there is little clay (< 1%) in the bed sediments. Channel abandonment was initiated by a series of unit bars that stalled and progressively blocked the anabranch entrance, together with dune deposition and stacking at the anabranch entrance and exit. Complete channel abandonment and subsequent fill of up to 3 m of sediment took approximately two years. Thirteen kilometres of ground‐penetrating radar surveys, coupled with 18 cores, were obtained over the channel fill and an adjacent 750 m long, 400 m wide, compound bar, enabling a quantitative analysis of the channel and bar deposits. Results show that, in terms of grain‐size trends, facies proportions and scale of deposits, there are only subtle differences between the channel fill and bar deposits which, therefore, renders them indistinguishable. Thus, it may be inappropriate to assign different geometric and sedimentological attributes to channel fill and bar facies in object‐based models of sandy braided river alluvial architecture.     

水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。